Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Triphenylphosphonium—Cyanometallate

Triphenylphosphonium—cyanometallates. Organophosphorus derivatives of transition metal complex cyanides

Phosphororganische Derivate von Übergangsmetall-Cyanokomplexen, 7. Mitt.

Abstract

The derivatives of cyano complex compounds of iron, cobalt and manganese with the triphenylphosphonium-cation were prepared and investigated by IR- andMössbauer-spectroscopic methods. The thermal decomposition of the triphenylphosphonium-cyanometallates leads to intermediates which can be isolated.

This is a preview of subscription content, log in to check access.

Literatur

  1. 2

    P. Rigo undA. Turco, Coord. Chem. Rev.8, 175 (1972).

  2. 3

    S. Papp undS. Czeglédi, Z. Naturforsch.32 b, 167 (1977).

  3. 4

    W. Beck undH. S. Smedal, Z. Naturforsch.20 b, 109 (1965).

  4. 5

    P. Gans, A. Sabatini undL. Sacconi, Inorg. Chem.5, 1877 (1966).

  5. 6

    D. F. Shriver undJ. Posner, J. Amer. Chem. Soc.88, 1672 (1966).

  6. 7

    A. N. Garg undP. S. Goel, J. Inorg. Nucl. Chem.31, 697 (1969).

  7. 8

    A. N. Garg undP. S. Goel, J. Inorg. Nucl. Chem.32, 1547 (1970).

  8. 9

    L. Korecz, P. Mag, S. Papp, B. Mohai undK. Burger, Radiochem. Radioanal. Letters10, 59 (1972).

Download references

Author information

Additional information

Als 6. Mitt. gilt:S. Papp undM. Pál, Magy. Kém. Folyóirat83, 346 (1977).

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Papp, S., Buza, S. Triphenylphosphonium—Cyanometallate. Monatshefte für Chemie 110, 377–385 (1979). https://doi.org/10.1007/BF00911925

Download citation

Key words

  • Mössbauer spectra
  • Thermal decomposition, triphenylphosphonium-cyanometallates
  • Triphenylphosphonium-cyanometallates, synthesis