Correlation of the nuclear quadrupole resonance frequencies of Cl35 of dihydrochlorides of certain phosphorus acids with the σφ constants of substituents on the phosphorus atom
Physical Chemistry
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Conclusions
Two linear relationships exist between the nuclear quadrupole resonance frequencies of Cl35 in dichlorides of certain phosphorus acids and the σφ constants of substituents at the phosphorus atom; one of them is formed by alkyldichlorophosphonates, while the other is given by compounds in which conjugation is possible between the substituent and the d-orbitals of phosphorus-alkyldichlorophosphates, aryl- and vinyldichlorophosphonates.
Keywords
Phosphorus Linear Relationship Resonance Frequency Dichloride Dihydrochlorides
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