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Reverse-disproportionation reaction of chelate zirconium compounds

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Summary

  1. 1.

    By reaction ofβ-diketones with zirconyl nitrate, zirconium bisacetylacetonate dinitrate and zirconium bisbenzoylacetonate were prepared.

  2. 2.

    By reaction ofβ-diketones with zirconyl nitrate in presence of sodium bicarbonate, zirconium trisacetylacetonate nitrate and zirconium trisbenzoylacetonate nitrate were prepared.

  3. 3.

    The reverse-disproportionation reaction is applicable to chelate zirconium compounds. Reaction of zirconium tetrakisacetylacetonate and of zirconium tetrakisbenzoylacetonate with the corresponding dinitrates gave the zirconium trisacylacetonate mononitrates.

  4. 4.

    The above-mentioned mono- and di-nitrates give double compounds with benzene and dioxane.

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Literature cited

  1. [1]

    R. Kh. Freidlina, E. M. Brainina, and A. N. Nesmeianov, Bull, Acad. Sci. USSR, Div. Chem. Sci. (1957), p. 36.

  2. [2]

    A. N. Nesmeianov, R. Kh. Freidlina, and E. M. Brainina, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1954), p. 987.

  3. [3]

    A. N. Nesmeianov, E. M. Brainina, and R. Kh. Freidlina, Bull. Acad. Sci. USSR, Div. Chem. Sci. (1955), p. 838.

  4. [4]

    D. C. Bradley, F. M. Halim, R. C. Mehrotra and W. Wardlaw, J. Chem. Soc. (1952), p. 4609.

  5. [5]

    G. Yantsch, J. prakt. Chem. 115, 7 (1927).

  6. [6]

    W. Dilthey, J. prakt. Chem. 111, 147 (1925).

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Brainina, E.M., Freidlina, R.K. & Nesmeianov, A.N. Reverse-disproportionation reaction of chelate zirconium compounds. Russ Chem Bull 7, 910–913 (1958). https://doi.org/10.1007/BF00911339

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Keywords

  • Sodium
  • Nitrate
  • Zirconium
  • Benzene
  • Bicarbonate