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Monatshefte für Chemie / Chemical Monthly

, Volume 110, Issue 5, pp 1113–1121 | Cite as

Charge-transfer complexes of cobaltocene and nickelocene with tetrachloromethane

  • Anna Jaworska-Augustyniak
  • Jan Wojtczak
Anorganische, Struktur- und Physikalische Chemie

Abstract

The photochemical properties of the systems cobaltocene—tetrachloromethane and nickelocene—tetrachloromethane in ethanol and cyclohexane were investigated; the equilibrium constants and molar extinction coefficients of the donor—acceptor complexes in these systems were determined.

Key words

Charge transfer complexes Cobaltocene Nickelocene 

Charge-Transfer Komplexe von Kobaltocen und Nickelocen mit Tetrachlorkohlenstoff

Zusammenfassung

Es wurden die photochemischen Eigenschaften der Systeme Kobaltocen−CCl4 und Nickelocen−CCl4 in Ethanol und Cyclohexen als Lösungsmittel untersucht. Die Gleichgewichtskonstanten und die molaren Extinctionskoeffizienten der Donor—Acceptor-Komplexe in diesen Systemen wurden bestimmt.

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Copyright information

© Springer-Verlag 1979

Authors and Affiliations

  • Anna Jaworska-Augustyniak
    • 1
  • Jan Wojtczak
    • 1
  1. 1.Photochemistry Laboratory, Institute of ChemistryAdam Mickiewicz UniversityPoznanPoland

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