The IR spectra in the region of the frequencies of the valence vibrations of CO and the proton magnetic resonance spectra of a series of derivatives of cyclopentadienylirondicarbonyl, containing a tin-iron bond, were studied.
On the basis of the data obtained on the frequencies, relative intensities of the IR bands, and the values of the chemical shifts in the NMR spectrum, the mechanism of transmission of the influence of substituents on the tin atom to the carbonyl ligands and protons of the cyclopentadienyl ring, as well as possible conformations of derivatives of the type of [C5H5(CO)2Fe]2SnX2, are discussed.
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A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and V. V. Skripkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1290 (1966).
A. N. Nesmeyanov, Yu. A. Chapovskii, B. V. Lokshin, L. V. Denisovich, and I. V. Polovyanyuk, Dokl. Akad. Nauk SSSR,174, 1342 (1967).
B. P. Biryukov, Yu. T. Struchkov, K. N. Anisimov, N. E. Kolobova, and V. V. Skripkin, Zh. strukt. Khim.,8, 556 (1967).
B. P. Biryukov, Yu. T. Struchkov, K. N. Anisimov, N, E. Kolobova, and V. V. Skripkin, Chem. Comm., 750 (1967); 159 (1968).
J. O'Connor and E. R. Corey, J. Inorg. and Nucl Chem.,6, 968 (1967).
M. A. Bush and P. Woodward, Chem. Comm.,4, 166 (1967).
N. Flitcroft, D. A. Harbourne, J. Paul, P. M. Tucker, and F. G. A. Stone, J. Chem. Soc., 3130 (1966).
V. I. Gol'danskii, B. V. Borshagovskii, E. F. Makarov, R. A. Stukan, K. N. Anisimov, N. E. Kolobova, and V. V. Skripkin, Zh. Teoret. i Éksperiment. Khimii,3, 478 (1967).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1024–1030, March, 1968.
In conclusion, the authors would like to express their deep gratitude to P. V. Petrovskii for taking the PMR spectra and his aid in discussing the spectra.
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Anisimov, K.N., Lokshin, B.V., Kolobova, N.E. et al. Spectroscopic study of derivatives of cyclo-pentadienylirondicarbonyl, containing an iron-tin bond. Russ Chem Bull 17, 978–981 (1968). https://doi.org/10.1007/BF00910827
- Proton Magnetic Resonance
- Chemical Shift
- Relative Intensity
- Proton Magnetic Resonance Spectrum