An investigation was made of the thermal decomposition of methylbistrifluoromethyl- and dimethyl(trifluoromethyl)-methoxides, which led to the formation of the corresponding tertiary alcohols.
In the dimethyl(trifluoromethyl)methoxide the trifluoromethyl group has pseudohalogen properties.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
I. L. Knunyants and Yu. A. Cheburkov, Dokl. AN SSSR,137, 1121 (1961).
S. Cristol and W. Norris, J. Am. Chem. Soc.75, 2645 (1953).
G. Bressanin and G. Segre, Gazz. chim. ital.41, 1, 671 (1911).
E. Fear, J. Thrower, and J. Veitch, J. Chem. Soc. 1322 (1958).
I. L. Knunyants, N. P. Gambaryan, and Ch'en Ch'ing-yun, Izv, AN SSSR, Otd. Khim. n. 686 (1960).
E. Gryszkiewicz-Trochimowski, A. Sporzynski, and J. Wnuk, Recueit trav. chim.66, 427 (1947).
About this article
Cite this article
Knunyants, I.L., Cheburkov, Y.A. & Makarov, Y.V. Thermal decomposition of alkoxides derived from tertiary alcohols containing trifluoromethyl groups. Russ Chem Bull 10, 1370–1373 (1961). https://doi.org/10.1007/BF00910112
- Thermal Decomposition