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Thermal decomposition of alkoxides derived from tertiary alcohols containing trifluoromethyl groups

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Summary

  1. 1.

    An investigation was made of the thermal decomposition of methylbistrifluoromethyl- and dimethyl(trifluoromethyl)-methoxides, which led to the formation of the corresponding tertiary alcohols.

  2. 2.

    In the dimethyl(trifluoromethyl)methoxide the trifluoromethyl group has pseudohalogen properties.

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Literature cited

  1. 1.

    I. L. Knunyants and Yu. A. Cheburkov, Dokl. AN SSSR,137, 1121 (1961).

  2. 2.

    S. Cristol and W. Norris, J. Am. Chem. Soc.75, 2645 (1953).

  3. 3.

    G. Bressanin and G. Segre, Gazz. chim. ital.41, 1, 671 (1911).

  4. 4.

    E. Fear, J. Thrower, and J. Veitch, J. Chem. Soc. 1322 (1958).

  5. 5.

    I. L. Knunyants, N. P. Gambaryan, and Ch'en Ch'ing-yun, Izv, AN SSSR, Otd. Khim. n. 686 (1960).

  6. 6.

    E. Gryszkiewicz-Trochimowski, A. Sporzynski, and J. Wnuk, Recueit trav. chim.66, 427 (1947).

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Knunyants, I.L., Cheburkov, Y.A. & Makarov, Y.V. Thermal decomposition of alkoxides derived from tertiary alcohols containing trifluoromethyl groups. Russ Chem Bull 10, 1370–1373 (1961). https://doi.org/10.1007/BF00910112

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Keywords

  • Alcohol
  • Dimethyl
  • Thermal Decomposition
  • Alkoxide
  • Methoxide