A study of the isotope exchange of the ethyl esters of α-brommercuryarylacetic acids with203Hg Br2 and 70% aqueous dioxane at 60°, made it possible to arrange the substituents in the following series in order of decreasing reaction rate: p-I, Br, Cl > p-F >H > o-CH3 > p-CH3> p-typet. C4H9.
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O. A. Reutov, V. I. Sokolov, and I. P. Beletskaya, Dokl. AN SSSR,136, No. 3, 631 (1960).
O. A. Reutov and V. I. Sokolov, Dokl. AN SSSR,136, No. 2, 366 (1961).
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F. T. Fang, J. K. Kochi, and G. S. Hammond, J. Am. Chem. Soc.80, 563 (1958).
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Reutov, O.A., Sokolov, V.I. & Beletskaya, I.P. Isotope exchange study of the e lectrophilic replacement reaction in a saturated carbon atom. Russ Chem Bull 10, 1328–1330 (1961). https://doi.org/10.1007/BF00910102
- Carbon Atom
- Ethyl Ester