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1-Chloro-3-(di)alkylamino-disilazanes. Chemistry of silicon-nitrogen compounds, CXVII

Beiträge zur Chemie der Silicium-Stickstoff-Verbindungen 117. Mitt.


The 1-chloro-3-(di)alkylamino-disilazanes1–18 were prepared according to equ. (2), characterized in their properties (Tab. 1) and confirmed in their structure (Tab. 2, 3). They could be transformed easily into disiltriazanes (equ. 3), but not be condensed into cyclotri- or-tetrasilazanes.

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  1. 4

    U. Wannagat, Chemiker-Ztg.97, 105 (1973).

  2. 5

    U. Wannagat undG. Schreiner, Mh. Chem.96, 1889 (1965).

  3. 6

    L. Gerschler undU. Wannagat, J. organometal. Chem.29, 217 (1971).

  4. 7

    U. Wannagat undG. Schreiner, Mh. Chem.96, 1895 (1965).

  5. 8

    U. Wannagat undE. Bogusch, Mh. Chem.102, 1806 (1971).

  6. 9

    me=Methyl,et=Äthyl,pr=n-Propyl,i pr=Isopropyl,bu=n-Butyl,t bu=tert. Butyl,hx=n-Hexyl,c hx=Cyclohexyl.

  7. 10

    U. Wannagat undD. Labuhn, unveröffentlicht; siehe auch3.

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116. Mitt.:U. Wannagat undD. Labuhn, Mh. Chem.104, 1453 (1973).

Sonderdrucke über Prof. Dr.U. Wannagat, Inst. f. Anorg. Chemie der Techn. Univ., Pockelsstraße 4, D-3300 Braunschweig, Bundesrepublik Deutschland.

Mit Auszügen aus der DissertationD. Labuhn, Techn. Univ. Braunschweig 1973.

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Wannagat, U., Labuhn, D. 1-Chlor-3-(di)alkylamino-disilazane. Monatshefte für Chemie 104, 1457–1463 (1973).

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