Monatshefte für Chemie / Chemical Monthly

, Volume 105, Issue 6, pp 1299–1305 | Cite as

IR- und Raman-Spektren einiger Kaliumpentafluorometallate-monohydrate

Untersuchungen über Fluorometallate(III), 7. Mitt.
  • P. Bukovec
  • B. Orel
  • J. Šiftar
Anorganische, Struktur- und Physikalische Chemie
Received:

Fluoro metallates(III), VII: IR- and Raman Spectra of some potassium pentafluorometallates monohydrates

Abstract

The IR- and Raman Spectra of several compounds of the stoichiometryM2IMIIIF5H2O and their deuterated analogs have been interpreted on the basis of their crystal structures. The compounds studied were divided into two classes regarding the bonding of water molecules. The main spectroscopic difference between the two classes was found in the region of H2O vibrations in good agreement with theoretical predictions. The metal—fluorine and metal—oxygene vibrations gave no direct information concerning the two types of water.

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Copyright information

© Springer-Verlag 1974

Authors and Affiliations

  • P. Bukovec
    • 1
  • B. Orel
    • 1
  • J. Šiftar
    • 1
  1. 1.Laboratorium für Anorganische Chemie und Institut “Jožef Stefan”Universität LjubljanaLjubljanaJugoslawien

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