The reactions of fluorine-containingβ-sultones with esters and acid chlorides of nitrous, phosphoric or phosphonic, sulfurous, sulfuric and sulfonic acids take place as transacylations, forming esters or acid chlorides of polyfluoroalkenylsulfuric acids and acid fluorides of the corresponding nitrogen, phosphorus or sulfur-containing acids.
Unsymmetrical dialkyl sulfates are characterized by twofold activity: alkylation takes place with the simpler alkyl radical; but acylation involves the alkoxyl group with the larger hydrocarbon residue.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1804.
I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1017.
I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1022.
I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1027.
C. Suter, Chemistry of Organic Sulfur Compounds,[Russian translation], Foreign Literature Press,1, 60 (1960).
M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1613.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2020–2024, September, 1967.
About this article
Cite this article
Sokol'skii, G.A., Belaventsev, M.A. & Knunyants, I.L. Fluorine-containingβ-sultones. Russ Chem Bull 16, 1935–1938 (1967). https://doi.org/10.1007/BF00909586