Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Fluorine-containingβ-sultones

Communication 22. The mechanism of formation of polyfluoroalkenylsulfuric acid derivatives

  • 17 Accesses

  • 3 Citations

Conclusions

  1. 1.

    The reactions of fluorine-containingβ-sultones with esters and acid chlorides of nitrous, phosphoric or phosphonic, sulfurous, sulfuric and sulfonic acids take place as transacylations, forming esters or acid chlorides of polyfluoroalkenylsulfuric acids and acid fluorides of the corresponding nitrogen, phosphorus or sulfur-containing acids.

  2. 2.

    Unsymmetrical dialkyl sulfates are characterized by twofold activity: alkylation takes place with the simpler alkyl radical; but acylation involves the alkoxyl group with the larger hydrocarbon residue.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. A. Sokol'skii, M. A. Belaventsev, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1804.

  2. 2.

    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1017.

  3. 3.

    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1022.

  4. 4.

    I. L. Knunyants, G. A. Sokol'skii, and M. A. Belaventsev, Izv. AN SSSR, Ser. khim.,1966, 1027.

  5. 5.

    C. Suter, Chemistry of Organic Sulfur Compounds,[Russian translation], Foreign Literature Press,1, 60 (1960).

  6. 6.

    M. A. Belaventsev, G. A. Sokol'skii, and I. L. Knunyants, Izv. AN SSSR, Ser. khim.,1965, 1613.

Download references

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2020–2024, September, 1967.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Sokol'skii, G.A., Belaventsev, M.A. & Knunyants, I.L. Fluorine-containingβ-sultones. Russ Chem Bull 16, 1935–1938 (1967). https://doi.org/10.1007/BF00909586

Download citation

Keywords

  • Nitrogen
  • Sulfate
  • Chloride
  • Ester
  • Phosphorus