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Infrared absorption spectra of zirconium rhodanide complexes

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Summary

  1. 1.

    A description is given of the infrared absorption spectra (400–4000 cm−1) of the compound ZrO(NCS)2 · MNCS · 2H2O, where M=NH4, K, Rb, Cs, or PyH, as well as of the compounds (PyH)2[Zr(NCS)6] · 2H2O and ZrOCl2 · 8H2O (in the sofid state).

  2. 2.

    The ZrO(NCS)2 · MNCS · 2H2O complexes contain the zirconyl group, ZrO, and monodentate rhodano-groups, bound with a zirconium atom through a nitrogen atom. Hydrogen bonds apparently exist in the compounds.

  3. 3.

    The compound ZrOCl2 · 8H2O does not contain the zirconyl group, in complete agreement with structural data.

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Kharitonov, Y.Y., Rozanov, I.A. Infrared absorption spectra of zirconium rhodanide complexes. Russ Chem Bull 11, 373–377 (1962). https://doi.org/10.1007/BF00909523

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Keywords

  • Hydrogen
  • Nitrogen
  • 2H2O
  • Zirconium
  • Hydrogen Bond