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Kinetics of dehydrogenation and dehydration of isopropyl alcohol on titanium dioxide (anatase)

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Summary

  1. 1.

    This is the first study that has been made of the detailed kinetics of the dehydrogenation and dehydration of isopropyl alcohol on TiO2, complicated by carbonation of the catalyst.

  2. 2.

    The carbonation of the TiO2 has little effect on the values of the relative adsorbtion coefficient of acetone and hydrogen.

  3. 3.

    The relative adsorbtion coefficients of acetone and water drop with increasing temperature (from 2.7 to 0.9 for acetone, and from 1.9 to 0.9 for water), but the coefficients of hydrogen and propylene do not change over the temperature range 280–310‡.

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Literature cited

  1. 1.

    F. Bischoff and H. Adkins, J. Amer. Chem. Soc.47, 807 (1925).

  2. 2.

    F. Bischoff and H. Adkins, J. Amer. Chem. Soc.46, 256 (1924).

  3. 3.

    A. M. Rubinshtein and S. G. Kulikov, Dokl. AN SSSR67, 1053 (1949).

  4. 4.

    A. M. Rubinshtein and S. G. Kulikov, Izv. AN SSSR, Otd. khim. n.1950, 84.

  5. 5.

    G. Schwab and E. Schwab, J. Amer. Chem. Soc.71, 1806 (1949).

  6. 6.

    C. I. Englder, J. Phys. Chem.21, 676 (1917).

  7. 7.

    Yu. A. Arbuzov and N. D. Zelinskii, Compt. rend.30, 717 (1941).

  8. 8.

    Küchi Ioschioka, Japanese patent 180692; October 20, 1949.

  9. 9.

    W. Krantz, US patent 2605238; July 29, 1950.

  10. 10.

    V. Johnson, British patent 680122; October 29, 1952.

  11. 11.

    F. Spangenberg, Industr. J. quim. Buenos Aires7, 393 (1945).

  12. 12.

    M. Brown and A. Vernon, Industr. and Engng. Chem.32, 534 (1940).

  13. 13.

    F. Gresham and M. Brunes, US patent 2422169; June 10, 1947.

  14. 14.

    K. Bunte and H. Bruckner, Brennstoff-Chemie22, 205 (1941).

  15. 15.

    V. C. F. Holm and R. W. Blue, Industr. and Engng. Chem.44, 107 (1952).

  16. 16.

    I. L. Sandler, J. Phys. Chem.58, 58 (1954).

  17. 17.

    K. Hauffe, Angew. Chemie67, 189 (1955).

  18. 18.

    A. A. Balandin, A. A. Tolstopyatova, and I. R. Konenko, Dokl. AN SSSR133, 130 (1960); Izv. AN SSSR, Otd. khim. n.1960, 2096.

  19. 19.

    G. Moger and W. Rouge, Angew. Chemie52, 637 (1939).

  20. 20.

    V. V. Patrikeev and V. A. Ferapontov, Peredovoi nauchno-tekhnich. i proizvodstven. opyt. No. P-57-75/11 (1957).

  21. 21.

    A. A. Balandin, Zh. obshch. khimii12, 153, 160 (1942).

  22. 22.

    A. A. Balandin, O. K. Bogdanova, and A. P. Shcheglova, Izv. AN SSSR, Otd. khim. n.1946, 464.

  23. 23.

    A. A. Balandin, Dokl. AN SSSR63, 33 (1948).

  24. 24.

    A. A. Tolstopyatova, A. A. Balandin, and é. N. Dmitriev, Izv. AN SSSR, Otd. khim. n. 1956, 1404.

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Tolstopyatova, A.A., Konenko, I.R. & Balandin, A.A. Kinetics of dehydrogenation and dehydration of isopropyl alcohol on titanium dioxide (anatase). Russ Chem Bull 10, 31–36 (1961). https://doi.org/10.1007/BF00909398

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Keywords

  • Hydrogen
  • Alcohol
  • TiO2
  • Titanium
  • Dioxide