Iron carbonyls as inhibitors of thiol addition to phenylacetylene and cis-trans isomerization of vinyl sulfides

  • I. I. Kandror
  • R.G. Petrova
  • P. V. Petrovskii
  • R. Kh. Freidlina
Brief Communications
Received:
  • 18 Downloads

Conclusions

  1. 1.

    Fe(CO)5 and [Fe(CO)3SC2H5]2 are effective inhibitors of radical isomerization of vinyl sulfides.

     
  2. 2.

    Fe(CO)5 and [Fe(CO)3SC2H5]2 inhibit the radical addition of thiols to phenylacetylene.

     
  3. 3.

    Mo(CO)6 and W(CO)6 display only a weak decelerating effect on the indicated reactions.

     

Keywords

Iron Sulfide Carbonyl Vinyl Thiol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. G. Petrova, I. I. Kandror, and R. Kh. Freidlina, Zh. Organ. Khim.,3, 1942 (1967).Google Scholar
  2. 2.
    I. I. Kandror, R. G. Petrova, and R. Kh. Freidlina, Izv, Akad. Nauk SSSR, Ser. Khim., 1373 (1968).Google Scholar
  3. 3.
    A. A. Oswald, K. Griesbaum, B. E. Hudson, Jr., and J. M. Bregman, J. Amer. Chem. Soc.,86, 2877 (1964).Google Scholar
  4. 4.
    T. A. Manuel, Advances in Organometal. Chem.,3, 181 (1965).Google Scholar
  5. 5.
    W. E. Truce and J. A. Simms, J. Amer. Chem. Soc.,78, 2756 (1956).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • I. I. Kandror
    • 1
  • R.G. Petrova
    • 1
  • P. V. Petrovskii
    • 1
  • R. Kh. Freidlina
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

Personalised recommendations