Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Homolytic alkylation of monofunctional derivatives of tetrahydrofuran with unsaturated compounds

Conclusions

  1. 1.

    In the homolytic alkylation of methyl tetrahydro-2-furoate, tetrahydrofurfuryl alcohol, and tetrahydrofurfuryl acetate with unsa.tura.ted compounds mainly 2,2-disubstituted tetrahydrofurans are formed.

  2. 2.

    By the free-radical addition of heptyl, benzyl, and cyclohexyl alcohols to acrylonitrile the correspondingγ-hydroxy nitriles were obtained.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. G. Galust'yan and Ch. Sh. Kadyrov, Khim. Geterotsikl. Soedin.,1967, No. 2, 376.

  2. 2.

    V. G. Glukhovtsev, G. I. Nikishin, S. S. Spektor, and S. V. Zakharova, Izv. Akad. Nauk SSSR, Ser. Khim.,1968, 1605.

  3. 3.

    G. I. Nikishin and V. D. Vorob'ev, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,1962, 1874.

  4. 4.

    G. I. Nikishin and V. D. Vorob'ev, Dokl. Akad. Nauk SSSR,136, 360 (1960).

  5. 5.

    C. D. Hurd and W. H. Sander, J. Amer. Chem. Soc.,74, 5324 (1952).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimtcheskaya, No. 7, pp. 1592–1596, July, 1969.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Glukhovtsev, V., Spektor, S. & Nikishin, G.I. Homolytic alkylation of monofunctional derivatives of tetrahydrofuran with unsaturated compounds. Russ Chem Bull 18, 1475–1478 (1969). https://doi.org/10.1007/BF00908755

Download citation

Keywords

  • Alcohol
  • Methyl
  • Acetate
  • Nitrile
  • Benzyl