In the homolytic alkylation of methyl tetrahydro-2-furoate, tetrahydrofurfuryl alcohol, and tetrahydrofurfuryl acetate with unsa.tura.ted compounds mainly 2,2-disubstituted tetrahydrofurans are formed.
By the free-radical addition of heptyl, benzyl, and cyclohexyl alcohols to acrylonitrile the correspondingγ-hydroxy nitriles were obtained.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimtcheskaya, No. 7, pp. 1592–1596, July, 1969.
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Glukhovtsev, V., Spektor, S. & Nikishin, G.I. Homolytic alkylation of monofunctional derivatives of tetrahydrofuran with unsaturated compounds. Russ Chem Bull 18, 1475–1478 (1969). https://doi.org/10.1007/BF00908755