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Determination of the basicity of ferrocenylcarbinol

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Conclusions

  1. 1.

    The extent of ionization and the basicity of ferrocenylcarbinol in sulfuric acid solutions were determined.

  2. 2.

    The ferrocenylmethyl cation is stable in mineral acid solutions, but forms a polymer in organic solvents in the presence of strong acids.

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Literature cited

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    J. H. Richards, E. A. Hill, D. C. Garwood, and M. Levenberg, Angew. Chemie,72, 38 (1960).

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    M. Rosenblum, Chemistry of the Iron Group Metallocenes, New York-London-Sydney, Chapter 1, p. 41 (1965).

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    N. C. Deno, J. J. Jaruzelski, and A. Schriesheim, J. Organ. Chem.,19, 155 (1954).

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    A. G. Evans, J. A. G. Jones, and G. O. Osborne, Trans. Faraday Soc.,50, 16 (1954).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2746–2748, December, 1967.

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Nesmeyanov, A.N., Reshetova, M.D. & Perevalova, E.G. Determination of the basicity of ferrocenylcarbinol. Russ Chem Bull 16, 2614–2615 (1967). https://doi.org/10.1007/BF00908510

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Keywords

  • Polymer
  • Sulfuric Acid
  • Acid Solution
  • Organic Solvent
  • Strong Acid