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Intramolecular condensation of nitro group with olefinic double bond

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Conclusions

A new reaction of nitro compounds was discovered on the example of the thermal isomerization of unsaturated nitrocarbinols and nitrodihydropyrans, consisting in the intramolecular addition of the nitro group to the olefinic double bond with the formation of the heterolytic 1,3,2-dioxazoline system.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 370–378, February, 1968.

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Simonyan, L.A., Gambaryan, N.P., Petrovskii, P.V. et al. Intramolecular condensation of nitro group with olefinic double bond. Russ Chem Bull 17, 357–363 (1968). https://doi.org/10.1007/BF00908443

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Keywords

  • Double Bond
  • Nitro Group
  • Nitro Compound
  • Thermal Isomerization
  • Olefinic Double Bond