Nine new optically active menthoxypropylalkyl(ethoxy)chlorosilanes and menthoxyethylethoxysilanes were obtained by the reaction of alkylhydrochlorosilanes and methylhydroethoxysilanes with menthyl allyl and menthyl vinyl ethers. Menthoxypropylmethylethoxysilanes were isolated when the menthoxypropylmethylchlorosilanes were etherified.
All of the obtained compounds possess a negative rotation and give smooth negative optical rotation dispersion curves, which are satisfactorily described by the Druid equation in the wavelength range 302–608 nm.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
K. A. Andrianov, A. A. Mamedov, L. M. Volkova, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1481.
A. Haller and F. March, Compt. rend.,138, 1665 (1904).
M. F. Shostakovskii, V. M. Vlasov, and A. K. Gorban, Zh. Obshch. Khim.,32, 1729 (1962).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 356–360, February, 1968.
About this article
Cite this article
Andrianov, K.A., Mamedov, A.A., Volkova, L.M. et al. Optically active menthoxyethyl- and methoxypropylalkylalkoxy(chloro)silanes. Russ Chem Bull 17, 345–348 (1968). https://doi.org/10.1007/BF00908440
- Wavelength Range