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Optically active menthoxyethyl- and methoxypropylalkylalkoxy(chloro)silanes

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  1. 1.

    Nine new optically active menthoxypropylalkyl(ethoxy)chlorosilanes and menthoxyethylethoxysilanes were obtained by the reaction of alkylhydrochlorosilanes and methylhydroethoxysilanes with menthyl allyl and menthyl vinyl ethers. Menthoxypropylmethylethoxysilanes were isolated when the menthoxypropylmethylchlorosilanes were etherified.

  2. 2.

    All of the obtained compounds possess a negative rotation and give smooth negative optical rotation dispersion curves, which are satisfactorily described by the Druid equation in the wavelength range 302–608 nm.

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Literature cited

  1. 1.

    K. A. Andrianov, A. A. Mamedov, L. M. Volkova, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1481.

  2. 2.

    A. Haller and F. March, Compt. rend.,138, 1665 (1904).

  3. 3.

    M. F. Shostakovskii, V. M. Vlasov, and A. K. Gorban, Zh. Obshch. Khim.,32, 1729 (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 356–360, February, 1968.

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Andrianov, K.A., Mamedov, A.A., Volkova, L.M. et al. Optically active menthoxyethyl- and methoxypropylalkylalkoxy(chloro)silanes. Russ Chem Bull 17, 345–348 (1968). https://doi.org/10.1007/BF00908440

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  • Ether
  • Silane
  • Vinyl
  • Wavelength Range
  • Chloro