Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Optically active menthoxyethyl- and methoxypropylalkylalkoxy(chloro)silanes

  • 20 Accesses

  • 1 Citations

Conclusions

  1. 1.

    Nine new optically active menthoxypropylalkyl(ethoxy)chlorosilanes and menthoxyethylethoxysilanes were obtained by the reaction of alkylhydrochlorosilanes and methylhydroethoxysilanes with menthyl allyl and menthyl vinyl ethers. Menthoxypropylmethylethoxysilanes were isolated when the menthoxypropylmethylchlorosilanes were etherified.

  2. 2.

    All of the obtained compounds possess a negative rotation and give smooth negative optical rotation dispersion curves, which are satisfactorily described by the Druid equation in the wavelength range 302–608 nm.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    K. A. Andrianov, A. A. Mamedov, L. M. Volkova, and E. I. Klabunovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1481.

  2. 2.

    A. Haller and F. March, Compt. rend.,138, 1665 (1904).

  3. 3.

    M. F. Shostakovskii, V. M. Vlasov, and A. K. Gorban, Zh. Obshch. Khim.,32, 1729 (1962).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 356–360, February, 1968.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Andrianov, K.A., Mamedov, A.A., Volkova, L.M. et al. Optically active menthoxyethyl- and methoxypropylalkylalkoxy(chloro)silanes. Russ Chem Bull 17, 345–348 (1968). https://doi.org/10.1007/BF00908440

Download citation

Keywords

  • Ether
  • Silane
  • Vinyl
  • Wavelength Range
  • Chloro