The amides and dialkylamides of barenecarboxylic acids undergo cleavage of the C-C bond between the barene nucleus and the amide group under the influence of NaNH2 in liquid ammonia with the formation of the corresponding barenes.
Potassium acetate causes cleavage of the C-C bond inα-barene ketones with the formation of the corresponding barene and acetic acid.
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Translated from Izvestiya Akademii NaukSSSR, Seriya Khimicheskaya, No. 6, pp. 1369–1371, June, 1967.
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Zakharkin, L.I., Podvisotskaya, L.S. Cleavage of c-c bond in amides of barenecarboxylic acids under the influence of sodium amide. Russ Chem Bull 16, 1322–1324 (1967). https://doi.org/10.1007/BF00908304
- Acetic Acid