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Effective charges of atoms and oxidative reactions

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Conclusions

  1. 1.

    The concept of the effective coordination charge was discussed. It was shown that in a series of inorganic crystals, the metal atoms may possess a negative effective charge.

  2. 2.

    A thermodynamic analysis was made of reactions of oxidation, and the energetic profitability of increasing the valence of the metal in the case when it possesses a negative effective coordination charge was substantiated.

  3. 3.

    The presence of correlation between the sign and magnitude of the effective charge and temperatures of oxidation reactions was demonstrated experimentally.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1214–1220, June, 1967.

In conclusion, the author would like to thank V. P. Kazakov for his valuable suggestions made during the discussion of this work.

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Batsanov, S.S. Effective charges of atoms and oxidative reactions. Russ Chem Bull 16, 1175–1180 (1967). https://doi.org/10.1007/BF00908268

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Keywords

  • Oxidation
  • Oxidation Reaction
  • Metal Atom
  • Thermodynamic Analysis
  • Effective Charge