Hydroboration of boron triallyl
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A solid polymer was obtained by the reaction of boron triallyl and diborane (2 ∶ 1) in ether solution.
When heated with n-butyl alcohol the polymer formed di-n-butoxy-1,5-diborocyclooctane and the tetra-n-butyl ester of propane-1,3-diboric acid. Propane-1,3-diboric acid was obtained by saponification of the latter.
KeywordsPolymer Alcohol Ether Ester Boron
- 1.B. M. Mikhailov and F. B. Tutorskaya, Izv. AN SSSR, Otd. Khim., 1127 (1959).Google Scholar