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β-Dicarbonyl compounds

Communication 17. Reaction of 2-acylcycloalkanones with hydrogen peroxide

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Summary

The presence of alkali suppresses the oxidative rearrangement of 2-acylcycloalkanones and favors the process of oxidative cleavage which occurs simultaneously.

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Vinogradova, L.P., Rudenko, B.A. & Zav'yalov, S.I. β-Dicarbonyl compounds. Russ Chem Bull 11, 1347–1352 (1962). https://doi.org/10.1007/BF00907984

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Keywords

  • Oxidative Cleavage
  • Oxidative Rearrangement