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Reactions of hydrazones and azines with metal salts

Communication 4. Reactions of azines of aldehydes and ketones with cupric salts
  • A. S. Gudkova
  • O. A. Reutov
  • M. Ya. Aleinikova
Organic and Biological Chemistry

Summary

In the reaction between the azines of acetaldehyde, acetone, butanone, and cyclohexanone and cupric chloride, bromide, and acetate in water complexes were formed of the azines with cuprous halides of composition
$$\left( {\begin{array}{*{20}c} R \\ {R_1 } \\ \end{array} \begin{array}{*{20}c} \setminus \\ / \\ \end{array} C = N - N = C\begin{array}{*{20}c} / \\ \setminus \\ \end{array} \begin{array}{*{20}c} R \\ {R_1 } \\ \end{array} } \right) \cdot nCuX,$$
in which X=Cl, Br, or I and n=2 or 3. These are analogous to the complexes prepared by us earlier from hydrazones and cupric halides.

Keywords

Acetate Acetaldehyde Chloride Acetone Bromide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. S. Gudkova and O. A. Reutov, Izv. AN SSSR. Otd. Khim., 1203 (1962).Google Scholar
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    A. N. Kost and I. I. Grandberg, Zh. Obshch. Khim.,26, 565 (1956).Google Scholar
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    A. N. Kost and I. I. Grandberg, Zh. Obshch. Khim.,26, 2320 (1956).Google Scholar
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    A. N. Kost and I. I. Grandberg, Zh. Obshch. Khim.,26, 1719 (1956).Google Scholar
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    A. N. Kost and I. I. Grandberg, Zh. Obshch. Khim.,25, 2067 (1955).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1963

Authors and Affiliations

  • A. S. Gudkova
    • 1
  • O. A. Reutov
    • 1
  • M. Ya. Aleinikova
    • 1
  1. 1.M. V. Lomonosov Moscow State University and Institute of Heteroorganic CompoundsAcademy of SciencesUSSR

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