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Successive elimination of the alcohol groups of 3,7-dimethyloctane-1,7-diol on a tricalcium phosphate catalyst

  • L. Kh. Freidlin
  • V. Z. Sharf
Brief Communications
  • 15 Downloads

Summary

  1. 1.

    The dehydration of 3,7-dimethyloctane-l,7-diol on a phosphate catalyst proceeds in stages: first to citronellol and then to 3,7-dimethyloctadiene.

     
  2. 2.

    The stepwise nature of the process is caused by the position of the hydroxyl groups (primary and tertiary) in the 3,7-dimethyloctane-l,7-diol molecule.

     

Keywords

Alcohol Phosphate Hydroxyl Dehydration Diol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    L. Kh. Friedlin and V. Z. Sharf, Kinetika i Kataliz,1, 247 (1960).Google Scholar
  2. 2.
    Z. Palfray, S. Sabetay, A. Rangel, Compt. rend.212, 911 (1941).Google Scholar
  3. 3.
    Dictionary of Organic Compounds [Russian translation] (IL, Moscow, 1949),1, pp. 934,558.Google Scholar

Copyright information

© Consultants Bureau 1961

Authors and Affiliations

  • L. Kh. Freidlin
    • 1
  • V. Z. Sharf
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences USSRUSSR

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