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High-temperature dehydrogenation of ethylbenzene

Summary

  1. 1.

    The kinetics of the thermal dehydrogenation of ethylbenzene at 660–740° were investigated.

  2. 2.

    The yield of styrene on the ethylbenzene that reacted was 58% at 660° and 70–75% at 690dg and 720dg.

  3. 3.

    The activation energy for the dehydrogenation of ethylbenzene was calculated; the value obtained was 44 ±2 kcal/mole.

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Literature cited

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    Lavrovskii, K. P., and Brodskii, A. M., Paper Read at Fourth International Petroleum Conference in Rome. Transactions of Congress [in Russian] (Gostoptekhizdat, 1956).

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    Balandin, A. A., Marukyan, G. M. and Tolstopyatova, A. A., Zhur. Priklad. Khim.19, No. 10–11, 1079 (1946).

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    Brodskii, A. M., Kalinenko, R. A., Lavrovskii, K. P. and Titov, V. B., Doklady Akad. Nauk SSSR116, 789:117, 1013 (1957).

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    Lavrovskii, K. P. and Brodskii, A. M., Trudy Inst. Nefti Akad Nauk SSSR4, 176 (1954).

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    Brooks, B. T. et al., Chemistry of Petroleum Hydrocarbons [Russian translation] (Gostoptekhizdat, 1958) Vol. 2, p. 15.

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Brodskii, A.M., Lavrovskii, K.P. & Filatova, E.D. High-temperature dehydrogenation of ethylbenzene. Russ Chem Bull 9, 1383–1386 (1960). https://doi.org/10.1007/BF00907673

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Keywords

  • Activation Energy
  • Styrene
  • Dehydrogenation
  • Ethylbenzene
  • Thermal Dehydrogenation