Pulse radiolysis of aqueous solutions of sulfuric acid

  • A. K. Pikaev
  • V. I. Zolotarevskii
Brief Communications


  1. 1.

    Using the method of pulse radiolysis in irradiated aqueous solutions of sulfuric acid, a short-lived optical absorption (maximum at 450 mμ due to the HSO4 (or SO 4 ) radical has been detected. The molar extinction coefficient of this product (∼1000 liter/mole · cm) and the velocity constant of the reaction between the OH radical and the HSO 4 (or SO 4 2− ) ion (∼106 liter/mole · sec) have been evaluated.



Aqueous Solution Sulfuric Acid Optical Absorption Extinction Coefficient Velocity Constant 
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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • A. K. Pikaev
    • 1
    • 2
  • V. I. Zolotarevskii
    • 1
    • 2
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Insitute of ElectrochemistryAcademy of Sciences of the USSRUSSR

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