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Synthesis of RAr2SbCl2 and Ar'Ar2SbCl2 by exchange of Ar2SbCl2 with HgR2 OR HgAr2

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Conclusions

  1. 1.

    A method has been proposed for the synthesis of pentavalent antimony compounds containing three identical or different groups by use of fully substituted mercury compounds.

  2. 2.

    The cis and trans isomers ofβ-chlorovinyldiphenylantimony dichloride have been prepared, and their structure has been established on the basis of their NMR and IR spectra.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 939–940, April 1969.

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Nesmeyanov, A.I., Borisov, A.E. Synthesis of RAr2SbCl2 and Ar'Ar2SbCl2 by exchange of Ar2SbCl2 with HgR2 OR HgAr2 . Russ Chem Bull 18, 853–855 (1969). https://doi.org/10.1007/BF00907058

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Keywords

  • Mercury
  • Antimony
  • Dichloride
  • Trans Isomer
  • Mercury Compound