A method has been proposed for the synthesis of pentavalent antimony compounds containing three identical or different groups by use of fully substituted mercury compounds.
The cis and trans isomers ofβ-chlorovinyldiphenylantimony dichloride have been prepared, and their structure has been established on the basis of their NMR and IR spectra.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 939–940, April 1969.
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Nesmeyanov, A.I., Borisov, A.E. Synthesis of RAr2SbCl2 and Ar'Ar2SbCl2 by exchange of Ar2SbCl2 with HgR2 OR HgAr2 . Russ Chem Bull 18, 853–855 (1969). https://doi.org/10.1007/BF00907058
- Trans Isomer
- Mercury Compound