Trinitromethane can be added to the C=N bond of phenylhydrazones of formaldehyde. Addition products were obtained from trinitromethane and methylene-2,4-dinitrophenylhydrazine and methylene-2, 2,4,6-trinitrophenylhydrazine.
By nitrating N-(2,4-dinitrophenyl)-N′-(2,2,2-trinitroethyl)hydrazine its N-nitro derivative was synthesized.
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Simonenko, L.S., Korsakova, I.S. & Novikov, S.S. Addition of trinitromethane to substituted phenylhydrazones of formaldehyde. Russ Chem Bull 18, 2160–2162 (1969). https://doi.org/10.1007/BF00906643
- Addition Product