Condensation of mercaptals with vinyl ethyl ether

  • B. M. Mikhailov
  • G. S. Ter-Sarkisyan
Brief Communications
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Summary

  1. 1.

    The condensation of the dimethyl mercaptals of cinnamaldehyde, benzaldehyde, andβ -cyclocitral with vinyl ethyl ether in the presence of acid catalysts was studied.

     
  2. 2.

    As a result of these reactions with one molecule of vinyl ethyl ether we obtained monothioacetals of mercaptoaldehydes RCH(SC2H5) CH2CH(OC2H5)SC2H5.

     
  3. 3.

    The addition of a second molecule of vinyl ethyl ether to 1-ethoxy-1,3-di(ethylmercapto)-3-phenylpropane resulted in elimination of the alkylmercapto group and formed 1,3-diethoxy-1,5-di(ethylmercapto)-5-phenylpentane.

     

Keywords

Ether Ethyl Dimethyl Vinyl Benzaldehyde 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

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Copyright information

© Consultants Bureau 1961

Authors and Affiliations

  • B. M. Mikhailov
    • 1
  • G. S. Ter-Sarkisyan
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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