Role of polar and steric factors in the reduction of ketones of the piperidine series
Organic and Biological Chemistry
Received:
- 17 Downloads
Conclusions
- 1.
The role of polar and steric factors during reduction ofγ-piperidones was investigated; the configuration of the alcohols obtained was determined.
- 2.
Alkyl substituents at the nitrogen atoms do not essentially influence the stereochemistry of the reduction of γpiperidones.
- 3.
All the four possible isomers of 1,2,3-trimethylpiperidol-4 and 1,2,5-trimethylpiperidol-4 were isolated.
Keywords
Nitrogen Alcohol Ketone Nitrogen Atom Piperidine
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
Literature cited
- 1.É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 1832 (1965).Google Scholar
- 2.É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 1826 (1965).Google Scholar
- 3.I. N. Nazarov and É. A. Mistryukov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 465 (1958).Google Scholar
- 4.I. N. Nazarov and B. A. Rudenko, Izv. Akad. Nauk SSSR. Otd. Khim. Nauk, 610 (1948).Google Scholar
- 5.I. N. Nazarov, E. M. Cherkasova, N. S. Prostakov, and I. I. Shvetsov, Zh.Obshch. Khim.,25, 2245 (1955).Google Scholar
- 6.G. T. Katvalyan and É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 2575 (1968).Google Scholar
- 7.É. A. Mistryukov, Izv. Akad. Nauk SSSR, Otd. Nauk, 623 (1961).Google Scholar
- 8.É. A. Mistryukov, Izv. Akad. Nauk SSSR, Sér. Khim., 2155 (1965).Google Scholar
- 9.É. A. Mistryukov and N. I. Aronova, Izv. Akad. Nauk SSSR, Ser. Khim., 143 (1967).Google Scholar
- 10.É. A. Mistryukov, J. Chromatography,9, 314 (1962).Google Scholar
- 11.É. A. Mistryukov and N. I. Aronova, Izv. Akad. Nauk SSSR, Ser. Khim., 783, 789 (1967).Google Scholar
- 12.N. I. Shvetsov and É. A. Mistryukov, Izv, Akad. Nauk SSSR, Otd. Khim. Nauk, 292 (1961).Google Scholar
- 13.É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 2006 (1965).Google Scholar
- 14.H. Haubenstock and E. L. Eliel, J. Amer. Chem. Soc.,84, 2368 (1962).Google Scholar
- 15.Tichy, Advances in Organic Chemistry, London-New York (1965), p. 240.Google Scholar
- 16.W. Cocker, T. B. H. McMurry and E. R. Simmons, J. Chem. Soc., 3022 (1965).Google Scholar
- 17.D. R. Howton, J. Organ. Chem.,10, 277 (1945).Google Scholar
- 18.É. A. Mistryukov, N. I. Aronova, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 932 (1961).Google Scholar
Copyright information
© Consultants Bureau 1970