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The probelem of determination of the direction of the mesomeric effect of substituents by the sutton rule

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Summary

We have considered a method for determining the direction of the mesomeric effect of substituents from the dipole moments of C6H5X and CH3X (according to Sutton) and have established the limits of its usefulness.

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Literature cited

  1. 1.

    L. E. Sutton, Proc. Roy. Soc.A133, 668 (1931).

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    C. K. Ingold, Chem. Rev.15, 225 (1934).

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    C. K. Ingold, Reaction Mechanism and Structure of Organic Compounds [Russian translation], IL, Moscow, 1959, pp. 87–88.

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    A. Audsley and F. R. Goss, J. Chem. Soc. 497 (1942).

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Voronkov, M.G. The probelem of determination of the direction of the mesomeric effect of substituents by the sutton rule. Russ Chem Bull 10, 1573–1575 (1961). https://doi.org/10.1007/BF00906157

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Keywords

  • Dipole Moment
  • Mesomeric Effect