A study was made of the homolytic reaction of trialkylethynylsilanes with mercaptans and thioacetic acid under the influence of ultraviolet light. It was shown that the direction of the reaction depends on the ratio of the reactants.
It was established that the second molecule of the mercaptan and thioacetic acid add differently to trialkylethynylsilanes.
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Komarov, N.V., Yarosh, O.G. & Kalabin, G.A. Reaction of trialkylethynylsilanes with mercaptans and thioacetic acid. Russ Chem Bull 16, 668–671 (1967). https://doi.org/10.1007/BF00906021
- Ultraviolet Light
- Thioacetic Acid
- Homolytic Reaction