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Borono and halo derivatives of tricarbonylcyclopentadienylmanganese and -rhenium

  • A. N. Nesmeyanov
  • N. E. Kolobova
  • Yu. V. Makarov
  • K. N. Anisimov
Organic and Biological Chemistry

Conclusions

  1. 1.

    By the action of tributyl borate on tricarbonyl(lithiocyclopentadienyl)manganese and -rhenium the corresponding boronic acids were prepared.

     
  2. 2.

    Some properties of these acids were studied. In an aqueous medium they are readily hydrolyzed with formation, respectively, of tricarbonylcyclopentadienylmanganese (TCM) and tricarbonyicyclopentadienylrhenium (TCR), and under given conditions the rate of hydrolysis of TCR-boronic acid is higher than the rate of hydrolysis of TCM-boronic acid.

     
  3. 3.

    The chloro and bromo derivatives of TCR and the already-known similar derivatives of TCM were prepared by the action of cupric halides on symmetrical mercury derivatives of TCM and TCR.

     
  4. 4.

    Bromo derivatives of TCM and TCR are inert in nucleophilic exchange reactions of halogen.

     

Keywords

Hydrolysis Mercury Manganese Borate Exchange Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • N. E. Kolobova
    • 1
  • Yu. V. Makarov
    • 1
  • K. N. Anisimov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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