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Redox reactions of π-cyclopentadienyltitanium (IV) halides

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Conclusions

  1. 1.

    The mechanism of polarographic reduction of π-cyclopentadienyl compounds of titanium, containing Ti-Halσ-bonds (C5H5)2TiX2 (X= F, Cl, Br, I), on a dropping mercury electrode was studied in aqueous alcohol and dimethylformamide.

  2. 2.

    It was shown, usingTiCl4, C5H5TiCl3, (C5H5)2TiCl2 as examples, that successive replacement of chlorine atoms in TiCl4 by a cyclopentadienyl ligand does not significantly influence the mechanism of the reduction of these compounds.

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Additional information

The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR from July 12, 1962, as the dissertation work of S. A. Smirnova.

The authors would like to thank O. V. Nogina and V. A. Dubovitskii for providing the compounds investigated in this work, and for their valuable advice during the discussion of the results.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1890–1897, September, 1969.

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Smirnova, S.A., Gubin, S.P. Redox reactions of π-cyclopentadienyltitanium (IV) halides. Russ Chem Bull 18, 1750–1756 (1969). https://doi.org/10.1007/BF00905800

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Keywords

  • Alcohol
  • Titanium
  • Mercury
  • Chlorine
  • Halide