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Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds

Communication 29. Structure of arylhydrazones of ω-methylglyoxal and the ethyl ester of diketobutyric acid

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Conclusions

  1. 1.

    The IR, NMR, UV, and Raman spectra of arylhydrazones ofω-methylglyoxal and diketobutyric acid were taken and discussed.

  2. 2.

    All the products considered possessed a hydrazone structure.

  3. 3.

    Arylhydrazones ofω-methylglyoxal are inclined to form intermolecular hydrogen bonds, while derivatives of diketobutyric acid in solutions represent a mixture of approximately equal amounts of the isomers with intramolecular hydrogen bonds formed by the hydrazone protons with the ketone and ester groups.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 729–735, April, 1968.

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Kitaev, Y.P., Nivorozhkin, L.E., Titova, Z.S. et al. Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 17, 705–710 (1968). https://doi.org/10.1007/BF00905736

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Keywords

  • Hydrogen
  • Ester
  • Hydrogen Bond
  • Carbonyl
  • Ketone