The IR, NMR, UV, and Raman spectra of arylhydrazones ofω-methylglyoxal and diketobutyric acid were taken and discussed.
All the products considered possessed a hydrazone structure.
Arylhydrazones ofω-methylglyoxal are inclined to form intermolecular hydrogen bonds, while derivatives of diketobutyric acid in solutions represent a mixture of approximately equal amounts of the isomers with intramolecular hydrogen bonds formed by the hydrazone protons with the ketone and ester groups.
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Kitaev, Y.P., Nivorozhkin, L.E., Titova, Z.S. et al. Study of the structure and reactivity of nitrogen-containing derivatives of carbonyl compounds. Russ Chem Bull 17, 705–710 (1968). https://doi.org/10.1007/BF00905736
- Hydrogen Bond