The thermal decomposition of bis(alkylamine)boronium alkanethiolates was studied. The decomposition results in the formation of the corresponding amine complexes of borane, 1,3,5-trialkylborazines, and bis(alkylamino)boranes.
The behavior of bis (t-butylthio)borane toward primary amines was studied. The course of the reaction depends on the reactant ratio, the order of mixing, and the nature of the amine.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 366–369, February, 1969.
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Shchegoleva, T.A., Shashkova, E.M. & Mikhailov, B.M. Organoboron compounds. Russ Chem Bull 18, 317–320 (1969). https://doi.org/10.1007/BF00905543
- Thermal Decomposition
- Primary Amine
- Reactant Ratio