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Organoboron compounds

Communication 194. Thermal decomposition of bis (alkylamine)boronium alkanethiolates

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Conclusions

  1. 1.

    The thermal decomposition of bis(alkylamine)boronium alkanethiolates was studied. The decomposition results in the formation of the corresponding amine complexes of borane, 1,3,5-trialkylborazines, and bis(alkylamino)boranes.

  2. 2.

    The behavior of bis (t-butylthio)borane toward primary amines was studied. The course of the reaction depends on the reactant ratio, the order of mixing, and the nature of the amine.

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Literature cited

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    V. D. Sheludyakov, T. A. Shchegoleva, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 632 (1964).

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    H. Nöth and H. Beyer, Chem. Ber.,93, 928 (1960).

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    N. E. Miller, B. L. Chamberland, and E. L. Muetterties, Inorg. Chem.,3, 1064 (1964).

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    B. M. Mikhailov, V. D. Sheludyakov, and T. A. Shchegoleva, Izv. Akad. Nauk SSSR, Otd. Khim, Nauk, 1559 (1962).

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    T. A. Shchegoleva, E. M. Shashkova, M. N. Bochkareva, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1306 (1968).

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    B. M. Mikhailov and T. A. Shchegoleva, Dokl. Akad. Nauk SSSR,131, 843 (1960).

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    B. M. Mikhailov and V. A. Dorokhov, Zh. Obshch. Khim.,32, 1511 (1962).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 366–369, February, 1969.

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Shchegoleva, T.A., Shashkova, E.M. & Mikhailov, B.M. Organoboron compounds. Russ Chem Bull 18, 317–320 (1969). https://doi.org/10.1007/BF00905543

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Keywords

  • Boronium
  • Thermal Decomposition
  • Borane
  • Primary Amine
  • Reactant Ratio