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Organoboron compounds

Communication 194. Thermal decomposition of bis (alkylamine)boronium alkanethiolates

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  1. 1.

    The thermal decomposition of bis(alkylamine)boronium alkanethiolates was studied. The decomposition results in the formation of the corresponding amine complexes of borane, 1,3,5-trialkylborazines, and bis(alkylamino)boranes.

  2. 2.

    The behavior of bis (t-butylthio)borane toward primary amines was studied. The course of the reaction depends on the reactant ratio, the order of mixing, and the nature of the amine.

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Literature cited

  1. 1.

    V. D. Sheludyakov, T. A. Shchegoleva, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 632 (1964).

  2. 2.

    H. Nöth and H. Beyer, Chem. Ber.,93, 928 (1960).

  3. 3.

    N. E. Miller, B. L. Chamberland, and E. L. Muetterties, Inorg. Chem.,3, 1064 (1964).

  4. 4.

    B. M. Mikhailov, V. D. Sheludyakov, and T. A. Shchegoleva, Izv. Akad. Nauk SSSR, Otd. Khim, Nauk, 1559 (1962).

  5. 5.

    T. A. Shchegoleva, E. M. Shashkova, M. N. Bochkareva, and B. M. Mikhailov, Izv. Akad. Nauk SSSR, Ser. Khim., 1306 (1968).

  6. 6.

    B. M. Mikhailov and T. A. Shchegoleva, Dokl. Akad. Nauk SSSR,131, 843 (1960).

  7. 7.

    B. M. Mikhailov and V. A. Dorokhov, Zh. Obshch. Khim.,32, 1511 (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 366–369, February, 1969.

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Shchegoleva, T.A., Shashkova, E.M. & Mikhailov, B.M. Organoboron compounds. Russ Chem Bull 18, 317–320 (1969).

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  • Boronium
  • Thermal Decomposition
  • Borane
  • Primary Amine
  • Reactant Ratio