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Reaction of esters of hypophosphorous acid with bis(diethylamino)methane and diethylaminomethyl ethyl ether

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Conclusions

  1. 1.

    A study was made of the reaction of alkyl hypophosphites with bis(diethylamino)methane and diethylaminomethyl ethyl ether. A number of esters of bis(α-aminomethyl)phosphonic acids was obtained.

  2. 2.

    Bis(α-aminomethyl)phosphonic acids are obtained in the case of the alkyl hypophosphites where the alkyl radical contains more than 6 C atoms. The alkyl hypophosphites with smaller radicals give either the esters ofα-aminomethylphosphonic acids or a mixture of the latter with the esters of bis (α-aminomethyl)phosphonic acids.

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Literature cited

  1. 1.

    B. E. Ivanov and T. I. Karpova, Izv. AN SSSR, Ser. Khim.,1964, 1230.

  2. 2.

    V. Ettel and J. Horak, Collection Czech. Chem. Commun.,26, 2087 (1961).

  3. 3.

    H. Schmidt, Chem. Ber.,81, 477 (1948).

  4. 4.

    J. Horak and V. Ettel, Collection Czech. Chem. Commun.,26, 2410 (1961).

  5. 5.

    T. Ya. Medved and M. I. Kabachnik, Dokl. AN SSSR,84, 717 (1952).

  6. 6.

    T. Ya. Medved and M. I. Kabachnik, Izv. AN SSSR, Otd. Khim. Nauk,1953, 868.

  7. 7.

    T. Ya. Medved and M. I. Kabachnik, Izv. AN SSSR, Otd. Khim. Nauk,1954, 314.

  8. 8.

    E. K. Fields, J. Am. Chem. Soc.,74, 1528 (1952).

  9. 9.

    W. M. Linfield, E. Jungermann, and A. T. Guttmann, J. Org. Chem.,26, 4088 (1961).

  10. 10.

    S. J. Fitch, J. Am. Chem. Soc.,86, 61 (1964).

  11. 11.

    E. E. Nifant'ev and L. P. Levitan, Zh. Obshch. Khimii,35, 758 (1965).

  12. 12.

    J. R. Van Wazer, Phosphorus and Its Compounds [Russian translation], IL (1962).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1498–1501, July, 1967.

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Ivanov, B.E., Kudryavtseva, L.A. Reaction of esters of hypophosphorous acid with bis(diethylamino)methane and diethylaminomethyl ethyl ether. Russ Chem Bull 16, 1447–1449 (1967). https://doi.org/10.1007/BF00905347

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Keywords

  • Ether
  • Ester
  • Methane
  • Ethyl
  • Small Radical