Relative reactivity of unsaturated germanium compounds in reactions with methyl radicals

  • N. S. Nametkin
  • S. I. Beilin
  • L. I. Tikhonova
  • S. G. Durgar'yan
Brief Communications
Received:
  • 14 Downloads

Conclusions

  1. 1.

    The reactivity of the multiple bond towards methyl radicals decreases in the order (CH3)3SiCH=CH2 > (CH3)3CCH=CH2 > (CH3)3GeCH=CH2.

     
  2. 2.

    Removal of a hydrogen atom from the “allyl ” position assumes considerable importance for α- and β-methyl-substituted vinylgermanes.

     

Keywords

Hydrogen Methyl Hydrogen Atom Germanium Allyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.
    N. S. Nametkin, S. G. Durgar'yan, L. I. Tikhonova, N. V. Ushkov, and M. V. Pozdnyakova, DAN SSSR,181, No. 6 (1968).Google Scholar
  2. 2.
    N. S. Nametkin, S. G. Durgar'yan, and L. I. Tikhonova, DAN SSSR,172, 615 (1967).Google Scholar
  3. 3.
    N. S. Nametkin, S. G. Durgar'yan, and L. I. Tikhonova, DAN SSSR,172, 867 (1967).Google Scholar
  4. 4.
    S. I. Beilin, N. A. Pokatilo, and B. A. Dolgoplosk. Vysokomolekul. Soed.,7, 1085 (1965).Google Scholar
  5. 5.
    S. I. Beilin, B. A. Dolgoplosk, and N. A. Pokatin, DAN SSSR,169, 1339 (1966).Google Scholar
  6. 6.
    A. M. Polyakova, V. V. Korshak, A. A. Sakharova, A. D. Petrov, V. F. Mironov, and G. I. Nikishin, Izv. AN SSSR, Otd. Khim. Nauk, 979 (1956).Google Scholar
  7. 7.
    V. V. Korshak, A. M. Polyakova, V. F. Mironov, and A. D. Petrov, Izv. AN SSSR, Otd. Khim. Nauk,1959, 178.Google Scholar
  8. 8.
    M. Kanazashi, Bull. Chem. Soc. Japan,28, 44 (1955).Google Scholar
  9. 9.
    D. Scifert, Organometallic Compounds with a Vinyl Group [in Russian], Mir (1964), p. 26.Google Scholar
  10. 10.
    R. P. Buckley, F. Leavitt, and M. Schwartz, J. Amer. Chem. Soc.,78, 5557 (1956).Google Scholar
  11. 11.
    L. Herk, A. Stefani, and M. Schwarz, J. Amer. Chem. Soc.,83, 3008 (1961).Google Scholar

Copyright information

© Consultants Bureau 1969

Authors and Affiliations

  • N. S. Nametkin
    • 1
  • S. I. Beilin
    • 1
  • L. I. Tikhonova
    • 1
  • S. G. Durgar'yan
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRUSSR

Personalised recommendations