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Reactions of aminophosphines with α,β-unsaturated aldehydes

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Conclusions

  1. 1.

    Reactions of secondary aminophosphines withα,β-unsaturated aldehydes proceed analogously to reactions with saturated aldehydes and ketones at the carbonyl group with formation of diaryl-α-(arylamino)-γ-[aryl(alkyl)]allylphosphine oxides.

  2. 2.

    Products analogous in structure are also formed in reactions with tertiary aminophosphines.

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Literature cited

  1. 1.

    V. S. Abramov and I. A. Il'ina, Dokl. Akad. Nauk SSSR,125, 1027 (1959).

  2. 2.

    A. N. Pudovik, S. A. Terent'eva, and É. S. Batyeva, Dokl. Akad. Nauk SSSR,175, 616 (1967).

  3. 3.

    R. F. Hudson, R. J. Searle, and F. H. Devitt, J. Chem. Soc., B1966, 789.

  4. 4.

    A. N. Pudovik and É. S. Batyeva, Zh. Obshch. Khim.,38, 285 (1968).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2391–2392, October, 1968.

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Pudovik, A.N., Batyeva, É.S. Reactions of aminophosphines with α,β-unsaturated aldehydes. Russ Chem Bull 17, 2265–2266 (1968). https://doi.org/10.1007/BF00904067

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Keywords

  • Oxide
  • Aldehyde
  • Carbonyl
  • Ketone
  • Carbonyl Group