Penta- and tetracoordinated phosphorous in reactions of biacetyl with diethylacetylphosphite and diethyl chlorophosphite
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Conclusions
Diethylacetyl phosphite and diethyl chlorophosphite react with biacetyl, intermediately forming, as do other derivatives of phosphorous acid, 1,3,2-dioxaphospholenes with a pentacoordinated phosphorous atom; the latter are rapidly transformed to noncyclic or cyclic derivatives of tetracoordinated phosphorous.
Keywords
Diethyl Phosphorous Acid Penta Phosphite Biacetyl
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