The IR and PMR spectra of a number of derivatives of manganese and rhenium carbonyls of the type of XC6H4COM(CO)5 and XC6H4M(CO)5 were measured.
On the basis of a comparison of the data on the IR spectra of a number of derivatives of the type of XMn(CO)5, the mechanism of the transmission of the influence of the substituent X to the carbonyl groups through the metal atom was discussed.
To explain the behavior of the frequenciesν C-O andν C=O in the IR spectra of derivatives of the type of RCOM(CO)5, a hypothesis was advanced on the intramolecular coordination of the oxygen of the acyl C=O group with the metal atom.
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Lokshin, B.V., Anisimov, K.N., Kolobova, N.E. et al. IR and PMR spectra of α-aromatic derivatives of manganese and rhenium carbonyls. Russ Chem Bull 17, 2318–2323 (1968). https://doi.org/10.1007/BF00903374
- Carbonyl Group
- Metal Atom