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Hydroxylamin—Hydroxynitron-Gleichgewichte

Hydroxylamine—Hydroxynitrone equilibria

Über Mannichbasen, 13. Mitt.

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Abstract

From the hydroxylaminomethylation product of 2-naphthol (3) and aliphatic resp. aromatic aldehydes resulting compounds were examined by NMR spectroscopy. In solution the products of formaldehyde, acetaldehyde and benzaldehyde show equilibria of cyclic hydroxylamine and hydroxynitrone forms2 resp.1, the state of which depends on the solvent; with the derivatives of p-nitro- and p-dimethylaminobenzaldehyde only the hydroxynitrone form1 d resp.1 e is detectable.

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Literatur

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    M. Betti, Gazz. Chim. Ital.36, 388 (1906).

  2. 3

    C. Runti undF. Collino, Ann. Chim. Appl.49, 1472 (1959).

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Author information

Correspondence to Prof. Dr. Hans Möhrle.

Additional information

Herrn Prof. Dr.E. Ziegler zur Vollendung des 65. Lebensjahres gewidmet.

12. Mitt.:H. Möhrle undM. Lappenberg, Chem. Ber.109, 1106 (1976).

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Möhrle, H., Lappenberg, M. & Wendisch, D. Hydroxylamin—Hydroxynitron-Gleichgewichte. Monatshefte für Chemie 108, 273–278 (1977). https://doi.org/10.1007/BF00901978

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