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To the theory of multiphonon radiationless transitions

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Abstract

A new method is proposed, allowing to express the probability of radiationless transitions in the harmonic approximation for the zeroth vibrational level. The results coincide entirely with those obtained by the density matrix method.

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Literature cited

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    Yu. E. Perlin, Usp. Fiz, Nauk,80, 557 (1963).

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    Sighart Fischer, J. Chem. Phys.,53, No. 6 (1970).

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    V. V. Svishchenko and A. F. Terpugova, Izv. VUZ, Fizika, No. 7, 62 (1973).

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    S. H. Lin and R. Bersohn, J. Chem. Phys.,48, 2732 (1968).

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Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 15–19, March, 1974.

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Svishchenko, V.V. To the theory of multiphonon radiationless transitions. Soviet Physics Journal 17, 303–306 (1974). https://doi.org/10.1007/BF00893939

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Keywords

  • Density Matrix
  • Matrix Method
  • Vibrational Level
  • Harmonic Approximation
  • Radiationless Transition