Vibrational spectra and force fields of pyridine complexes of zinc halides
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Abstract
A complete calculation is presented for the vibrational spectrum for these complexes, together with an interpretation; zeroth approximation was the force field for the pyridine ring and the corresponding tetrahedral ions. The self-consistent method has been used to determine the force-constant system for the complexes. A new assignment is given for the low vibration frequencies, which differs from those proposed previously from model calculations. A discussion is also given of methods of calculating the spectra of complexes containing aromatic ligands.
Keywords
Zinc Pyridine Model Calculation Force Field Halide
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© Plenum Publishing Corporation 1976