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Hydrolytic cocondensation of trichloro (3,3,3-trifluoropropyl) silane with dichlorodimethyl-, dichloromethylphenyl-, and dichloromethyl (3, 3, 3 -trifluoropropyl)-silanes

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Conclusions

  1. 1.

    The hydrolytic cocondensation of trichloro (3,3,3-trifluoropropyl) silane with dichlorodimethyl-, dichloromethylphenyl-, and dichloromethyl (3,3,3-trifluoropropyl)-silanes was studied for the first time, and polyfluoroorganosiloxane resins were obtained.

  2. 2.

    Investigation of the thermal stabilities of the resins obtained showed that they do not decompose below 350–435° in air and below 460° in argon.

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Literature cited

  1. 1.

    K. A. Andrianov, D. Ya. Zhinkin, and A. G. Kuznetsova, Zh. obshch. khimii,29, 1504 (1959).

  2. 2.

    K. A. Andrianov, Organosilicon Compounds [in Russian], Goskhimizdat, Moscow (1955), pp. 324, 364.

  3. 3.

    A. M. Geyer, R. N. Haszeldine, K. Leedham, and R. I. Marklow, J. Chem. Soc.,1957, 4472.

  4. 4.

    K. A. Andrianov and I. F. Manucharova, Izv. AN SSSR, Otd. khim. n.,1962, 420.

  5. 5.

    V. P. Bychkov and A. S. Khristianov, Zavodsk. laborat.,29, 1267 (1962).

  6. 6.

    K. A. Andrianov, Polymers with Inorganic Main Chains [in Russian], Izd. AN SSSR, Moscow (1962), p. 141, 213.

  7. 7.

    A. D. Petrov, V. A. Ponomarenko, and G. V. Odabashyan, Izv. AN SSSR, Otd. khim. n.,1962, 174.

  8. 8.

    German Pat. 1044814 (1958); Chem. Abstrs.,55, 3433 (1961).

  9. 9.

    A. L. Klebanskii, Yu. A. Yuzhelevskii, É V. Kogan, and E. G. Kagan, Zh. obshch. khimii,32, 323 (1962).

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Additional information

Translation from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2128–2135, December, 1966.

We thank B. V. Lopatin and L. V. Orlova for the spectral analysis of the polymers and A. D. Snegova for the chromatographic analysis of the monomers.

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Ponomarenko, V.A., Khomutova, N.M. & Manucharova, I.F. Hydrolytic cocondensation of trichloro (3,3,3-trifluoropropyl) silane with dichlorodimethyl-, dichloromethylphenyl-, and dichloromethyl (3, 3, 3 -trifluoropropyl)-silanes. Russ Chem Bull 15, 2061–2066 (1966). https://doi.org/10.1007/BF00867699

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Keywords

  • Silane
  • Argon
  • Thermal Stability
  • Trichloro
  • Dichloromethyl