Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Effect of fillers on the structure and properties of cured resins

1. Thermal and elastic properties of filled epoxy resin

Abstract

The elastic (modulus of elasticity and equilibrium high-elastic modulus) and thermal (volume coefficients of thermal expansion below and above the glass transition temperature) properties of compositions based on ÉD-5 epoxy resin cured with polyethylenepolyamine have been investigated. Quartz powder and aluminoborosilicate glass powder were employed as fillers at concentrations from 0 to 0.413. The thermal expansion coefficients of the compositions were studied in a dilatometer, in which the specimen is free of mechanical loads. The Young's modulus at 25°C and the equilibrium high-elastic modulus at 125°C of the compositions were determined in the compression regime in an instrument based on the IZV-2 optical length gage. The thermal expansion coefficients of the polymer matrix were calculated with allowance for the elastic properties of the resin and the filler. It is shown that, as the filler concentration increases, the thermal and elastic properties of the resin in the filled system change. This can be interpreted as a change in the properties of the resin as it approaches the surface of the filler particles. Increased interaction between the filler surface and the epoxy resin tends to stiffen the polymer network.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    Yu. S. Lipatov and G. M. Pavlyuchenko, VMS,2, 1564 (1960).

  2. 2.

    Yu. S. Lipatov, Ya. P. Vasilenko, and T. É. Lipatova, VMS,5, 290 (1963).

  3. 3.

    Yu. S. Lipatov, Physico-Chemistry of Filled Polymers [in Russian], Kiev (1967).

  4. 4.

    E. B. Trostyanskaya and A. M. Poimanov, Mekhan. Polim., No. 3, 8 (1965).

  5. 5.

    E. B. Trostyanskaya and P. G. Babaevskii, Mekhan. Polim., No. 6, 1033 (1968).

  6. 6.

    T. K. Kwei, J. Polym. Sci.,A9, 3229 (1965).

  7. 7.

    V. M. Levin, Inzh. Zh. MTT, No. 1 (1967).

  8. 8.

    Z. Hashin, J. Appl. Mech.,E, No. 1, 29 (1962).

  9. 9.

    N. I. Kitaigorodskii (editor), Glass Technology [in Russian], Moscow (1961).

  10. 10.

    G. W. C. Kaye and T. H. Laby, Tables of Physical and Chemical Constants, Wiley, New York (1959).

  11. 11.

    A. M. Poimanov, Candidate's dissertation, Moscow (1965).

  12. 12.

    J. D. Ferry, Viscoelastic Properties of Polymers, Wiley, New York (1961).

  13. 13.

    P. Simha and P. Boyer, J. Chem. Phys.,37, 5 (1962).

  14. 14.

    I. Furukawa, T. Saegusa, T. Tsuruta, and G. Kakagowa, Makromolec. Chem.,31, 25 (1959).

Download references

Additional information

Scientific Research Institute of Precision Technology, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1018–1022, November–December, 1969.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Trostyanskaya, E.B., Poimanov, A.M., Nosov, E.F. et al. Effect of fillers on the structure and properties of cured resins. Polymer Mechanics 5, 905–909 (1969). https://doi.org/10.1007/BF00864670

Download citation

Keywords

  • Thermal Expansion
  • Glass Transition
  • Glass Transition Temperature
  • Elastic Property
  • Mechanical Load