A study was made of the x-ray photoelectron spectra of Rh(I) and Rh(III) trifluoroacetate complexes. It was shown by using the Cls bond energies of the carboxylate carbon atom as a basis that bridging and monodentate coordination of the trifluoroacetate group could be distinguished with high resolution.
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N. F. Gol'dshleger,Oxid. Comm. 13, No. 1, 129 (1990).
N. F. Gol'dshleger, A. P. Moravskii, and Yu. M. Shul'ga,Izv. Akad. Nauk, Ser. Khim., No. 1, 258 (1991).
A. I. Nefedov,X-Ray Spectroscopy of Chemical Compounds [in Russian], Khimiya, Moscow (1984).
C. D. Garner and B. Hughes,Adv. Inorg. Radiochem. 17, 1 (1975).
B. I. Azbel, N. F. Gol'dshleger, M. L. Khidekel, V. I. Sokol, and M. A. Porai-Koshits,J. Mol. Cat. 40, 57 (1987).
V. I. Rubtsov and Yu. M. Shul'ga,Fiz. Tverd. Tela 32, 1323 (1990).
N. F. Gol'dshleger, B. I. Azbel', A. A. Grigor'ev, I. G. Sirotina, and M. L. Khidekel',Izv. Akad. Nauk, Ser. Khim., No. 3, 635 (1982).
Institute of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1549–1551, July, 1992.
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Shul'ga, Y.M., Gol'dshleger, N.F., Rubtsov, V.I. et al. X-ray photoelectron spectra of Rh(III) trifluoroacetate. Russ Chem Bull 41, 1193–1195 (1992). https://doi.org/10.1007/BF00864180
- photoelectron spectra
- Rh(III) trifluoroacetate