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X-ray photoelectron spectra of Rh(III) trifluoroacetate


A study was made of the x-ray photoelectron spectra of Rh(I) and Rh(III) trifluoroacetate complexes. It was shown by using the Cls bond energies of the carboxylate carbon atom as a basis that bridging and monodentate coordination of the trifluoroacetate group could be distinguished with high resolution.

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Institute of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1549–1551, July, 1992.

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Shul'ga, Y.M., Gol'dshleger, N.F., Rubtsov, V.I. et al. X-ray photoelectron spectra of Rh(III) trifluoroacetate. Russ Chem Bull 41, 1193–1195 (1992).

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  • photoelectron spectra
  • Rh(III) trifluoroacetate