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Organosilicon and organophosphorus compounds with pseudohalide groups

3. Reactions of alkoxydimethylsilyl cyanides with tetracoordinated phosphorus halides

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Abstract

The reactions of alkoxydimethylsilyl cyanides with some tetracoordinated phosphorus chlorides and fluorides were investigated. It was shown that the investigated reactions are realized primarily with the replacement of two halogen atoms by functional groups. The transformations of the phosphorus acid cyanides obtained with metal fluorides were studied.

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Additional information

For previous communication, see [1].

Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 187–191, January, 1992.

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Krolevets, A.A., Antipova, V.V., Petrovskii, P.V. et al. Organosilicon and organophosphorus compounds with pseudohalide groups. Russ Chem Bull 41, 153–157 (1992). https://doi.org/10.1007/BF00863934

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Keywords

  • silyl cyanides
  • phosphorus(IV) halides
  • substitution reactions
  • metal fluorides