The reactions of alkoxydimethylsilyl cyanides with some tetracoordinated phosphorus chlorides and fluorides were investigated. It was shown that the investigated reactions are realized primarily with the replacement of two halogen atoms by functional groups. The transformations of the phosphorus acid cyanides obtained with metal fluorides were studied.
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Krolevets, A.A., Antipova, V.V., Petrovskii, P.V. et al. Organosilicon and organophosphorus compounds with pseudohalide groups. Russ Chem Bull 41, 153–157 (1992). https://doi.org/10.1007/BF00863934
- silyl cyanides
- phosphorus(IV) halides
- substitution reactions
- metal fluorides