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Synthesis and properties of fluoronitroalcohols

Communication 3. 4-Fluoro-2,2,4,4-tetranitro-1-butanol, some of its esters and reactions

Conclusions

  1. 1.

    4-Fluoro-2,2,4,4-tetranitro-1-butanol and some of its esters, Michael reaction adducts, were prepared by aqueous fluorination with elementary fluorine.

  2. 2.

    1-Fluoro-1,1,3,3-tetranitropropane was obtained from 4-fluoro-2,2,4,4-tetranitro-1-butanol by the formaldehyde elimination reaction.

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Literature cited

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    L. T. Eremenko, G. V. Oreshko, and L. I. Berezina, Izv. Akad. Nauk SSSR, Ser. Khim., 2307 (1968).

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    L. T. Eremenko and F. Ya. Natsibullin, Izv. Akad. Nauk SSSR, Ser. Khim., 912 (1968).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2268–2271, October, 1970.

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Eremenko, L.T., Oreshko, G.V. & Berezina, L.I. Synthesis and properties of fluoronitroalcohols. Russ Chem Bull 19, 2131–2134 (1970). https://doi.org/10.1007/BF00861483

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Keywords

  • Ester
  • Formaldehyde
  • Adduct
  • Fluorine
  • Elimination Reaction