Investigation of the solvation of certain trimethyltin compounds by the proton magnetic resonance method

  • L. A. Fedorov
  • D. N. Kravtsov
  • A. S. Peregudov
  • É. I. Fedin
  • E. M. Rokhlina
Physical Chemistry
Received:
  • 16 Downloads

Conclusions

  1. 1.

    The chemical shifts and spin-spin interaction constants of derivatives of trimethyltin (CH3)3SnR and (CH3)3SnX in various solvents were investigated by the proton magnetic resonance method.

     
  2. 2.

    Depending on the nature of the substituent and the medium, the mechanism of the interaction of the solvent with the organotin compound may vary: polarization, solvation, or summary.

     
  3. 3.

    The structure of the solvating molecule (CH3)3SnX in solution was discussed. Additional conformations of the formation of stable particles containing a pentacoordinated metal atom in solvating media were found.

     

Keywords

Proton Magnetic Resonance Chemical Shift Metal Atom Solvate Molecule Interaction Constant 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • L. A. Fedorov
    • 1
  • D. N. Kravtsov
    • 1
  • A. S. Peregudov
    • 1
  • É. I. Fedin
    • 1
  • E. M. Rokhlina
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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