Catalysis of the reaction of methallyl chloride with CCl4 by some iron compounds or the system: Fe(CO)5-solvent

  • R. D. Ismailov
  • A. E. Zolotarev
  • B. A. Englin
Organic and Biological Chemistry
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Conclusions

  1. 1.

    A study was made of the catalytic effect of Fe(CO)5, Fe2(CO)9, Fe(acetylacetonate)3, FeCl3,π-C3H5Fe(CO)3I, and the system Fe(CO)5-solvent on the rate and direction of the radical reaction of methallyl chloride with CCl4 at 95°.

     
  2. 2.

    All of the catalysts, especially FeCl3, proved to be effective in ligand transfer and suppressed the development of the kinetic chain involving the free chlorine atom. The maximum rate of the process was observed with Fe(CO)5. Tetrahydrofuran, isopropanol and dimethylformamide possessed a high cocatalytic activity.

     

Keywords

Iron Chloride Catalysis Chlorine Isopropanol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • R. D. Ismailov
    • 1
  • A. E. Zolotarev
    • 1
  • B. A. Englin
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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